[Ru(arene)(diamine)] catalysts in ionic liquids: recyclable catalytic systems for transfer hydrogenation

被引：14

作者：

Joerger, Jean-Michel

Paris, Jean-Marc

Vaultier, Michel ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Chim, CNRS, UMR 6510, Campus Beaulieu,Av Gen Leclerc, F-35042 Rennes, France

[2] Rhodia CR Lyon, F-69192 St Fons, France

来源：

ARKIVOC | 2006年

关键词：

asymmetric transfer hydrogenation; ionic liquids; catalyst recycling;

D O I：

10.3998/ark.5550190.0007.410

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[Ru(arene)(diamine)] catalysts have been immobilized in a variety of ionic liquids for asymmetric transfer hydrogenation of acetophenone. Catalyst recycling is possible with several ionic liquids, and enantiomeric excess is well maintained.

引用

页码：152 / 160

页数：9

共 60 条

[1]

*ADV CHEM DEV INC, ACD PKA VERS 8 02

[2] Ionic liquids and chirality: opportunities and challenges [J].

Baudequin, C ;

Baudoux, J ;

Levillain, J ;

Cahard, D ;

Gaumont, AC ;

Plaquevent, JC .

TETRAHEDRON-ASYMMETRY, 2003, 14 (20) :3081-3093

[3] Synthesis and evaluation of a chiral heterogeneous transfer hydrogenation catalyst [J].

Bayston, DJ ;

Travers, CB ;

Polywka, MEC .

TETRAHEDRON-ASYMMETRY, 1998, 9 (12) :2015-2018

[4] Enantioselective catalytic asymmetric hydrogenation of ethyl acetoacetate in room temperature ionic liquids [J].

Berthod, M ;

Joerger, JM ;

Mignani, G ;

Vaultier, M ;

Lemaire, M .

TETRAHEDRON-ASYMMETRY, 2004, 15 (14) :2219-2221

[5] Hydrophobic, highly conductive ambient-temperature molten salts [J].

Bonhote, P ;

Dias, AP ;

Papageorgiou, N ;

Kalyanasundaram, K ;

Gratzel, M .

INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178

[6] Synthesis of water-soluble aminosulfonamide ligands and their application in enantioselective transfer hydrogenation [J].

Bubert, C ;

Blacker, J ;

Brown, SM ;

Crosby, J ;

Fitzjohn, S ;

Muxworthy, JP ;

Thorpe, T ;

Williams, JMJ .

TETRAHEDRON LETTERS, 2001, 42 (24) :4037-4039

[7] Synthesis of dendritic catalysts and application in asymmetric transfer hydrogenation [J].

Chen, YC ;

Wu, TF ;

Jiang, L ;

Deng, JG ;

Liu, H ;

Zhu, J ;

Jiang, YZ .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (03) :1006-1010

[8] Multiple dendritic catalysts for asymmetric transfer hydrogenation [J].

Chen, YC ;

Wu, TF ;

Deng, JG ;

Liu, H ;

Cui, X ;

Zhu, J ;

Jiang, YZ ;

Choi, MCK ;

Chan, ASC .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (15) :5301-5306

[9] Dendritic catalysts for asymmetric transfer hydrogenation [J].

Chen, YC ;

Wu, TF ;

Deng, JG ;

Liu, H ;

Jiang, YZ ;

Choib, MCK ;

Chan, ASC .

CHEMICAL COMMUNICATIONS, 2001, (16) :1488-1489

[10] Ruthenium-catalyzed asymmetric reduction of 1,3-diketones using transfer hydrogenation [J].

Cossy, J ;

Eustache, F ;

Dalko, PI .

TETRAHEDRON LETTERS, 2001, 42 (30) :5005-5007

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