Vibrational excitation in C 1s and O 1s photoionization of CO

被引：36

作者：

Kempgens, B ^{[1
]}

Maier, K ^{[1
]}

Kivimaki, A ^{[1
]}

Koppe, HM ^{[1
]}

Neeb, M ^{[1
]}

机构：

[1] UNIV ROMA TOR VERGATA,DEPT CHEM SCI & TECHNOL,I-00133 ROME,ITALY

来源：

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS | 1997年 / 30卷 / 21期

关键词：

D O I：

10.1088/0953-4075/30/21/005

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The C 1s and O 1s photoelectron spectra of the CO molecule have been measured with high resolution. The vibrational spacing of the O 1s(-1) state (226 +/- 7 meV) is significantly lower than in the C 1s(-1) state and in the molecular ground state. Compared to the groundstate equilibrium C-O distance of 1.128 Angstrom, we extract from the analysis of the Franck-Condon factors bond lengths of 1.079(2) Angstrom and 1.167(4) Angstrom for the C 1s and O 1s core-ionized states, respectively.

引用

页码：L741 / L747

页数：7

共 24 条

[11] VIBRATIONAL AND LIFETIME LINE BROADENINGS IN ESCA [J].

GELIUS, U ;

SVENSSON, S ;

SIEGBAHN, H ;

BASILIER, E ;

FAXALV, A ;

SIEGBAHN, K .

CHEMICAL PHYSICS LETTERS, 1974, 28 (01) :1-7

[12]

GELIUS U, 1974, J ELECTRON SPECTROSC, V2, P405

[13]

Huber KP, 1979, MOL SPECTRA MOL STRU, DOI [10.1007/978-1-4757-0961-2_2, DOI 10.1007/978-1-4757-0961-2_2]

[14] Vibrationally resolved O is photoelectron spectrum of CO2: Vibronic coupling and dynamic core-hole localization [J].

Kivimaki, A ;

Kempgens, B ;

Maier, K ;

Koppe, HM ;

Piancastelli, MN ;

Neeb, M ;

Bradshaw, AM .

PHYSICAL REVIEW LETTERS, 1997, 79 (06) :998-1001

[15] Autoionisation of doubly excited states in the C 1s photoexcitation of CO [J].

Koppe, HM ;

Kempgens, B ;

Kilcoyne, ALD ;

Feldhaus, J ;

Bradshaw, AM .

CHEMICAL PHYSICS LETTERS, 1996, 260 (1-2) :223-228

[16]

Koppe HM, 1995, J ELECTRON SPECTROSC, V75, P97, DOI 10.1016/0368-2048(95)02391-7

[17]

KUCHIEV MY, 1986, ZH EKSP TEOR FIZ, V63, P986

[18] VIBRATIONALLY RESOLVED THRESHOLD PHOTOEMISSION OF N2 AND CO AT THE N-K EDGE AND C-K EDGE [J].

MEDHURST, LJ ;

HEIMANN, PA ;

SIGGEL, MRF ;

SHIRLEY, DA ;

CHEN, CT ;

MA, Y ;

MODESTI, S ;

SETTE, F .

CHEMICAL PHYSICS LETTERS, 1992, 193 (06) :493-498

[19]

MULLER J, 1980, P NATO ADV STUDY I B, V90, P221

[20] APPROXIMATE FORMULAS FOR FRANCK-CONDON FACTORS [J].

NICHOLLS, RW .

JOURNAL OF CHEMICAL PHYSICS, 1981, 74 (12) :6980-6981

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