MoS2 hierarchical hollow cubic cages assembled by bilayers:: one-step synthesis and their electrochemical hydrogen storage properties

被引:143
作者
Ye, Lina [1 ]
Wu, Changzheng [1 ]
Guo, Wen [1 ]
Xie, Yi [1 ]
机构
[1] Univ Sci & Technol China, Dept Nanomat & Nanochem, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
关键词
D O I
10.1039/b610601c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Micrometer scaled MoS2 hierarchical hollow cubic cages assembled by bilayers can be synthesized via a one-step self-assembly coupled with intermediate crystal templating process without any surfactant, in which the intermediate K2NaMoO3F3 crystal formed in-situ and then served as the self-sacrificed template based on the Kirkendall Effect; The MoS2 hierarchical hollow cubic cages were employed for electrochemical hydrogen storage with a high capacity of 375 mAh g(-1) due to the more active edges exposing on the upright-standing nanoplates.
引用
收藏
页码:4738 / 4740
页数:3
相关论文
共 34 条
[31]   Monodisperse spherical colloids of Pb and their use as chemical templates to produce hollow particles [J].
Wang, YL ;
Cai, L ;
Xia, YN .
ADVANCED MATERIALS, 2005, 17 (04) :473-+
[32]   Morphosynthesis of rhombododecahedral silver cages by self-assembly coupled with precursor crystal templating [J].
Yang, JH ;
Qi, LM ;
Lu, CH ;
Ma, JM ;
Cheng, HM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (04) :598-603
[33]   Formation of hollow nanocrystals through the nanoscale Kirkendall Effect [J].
Yin, YD ;
Rioux, RM ;
Erdonmez, CK ;
Hughes, S ;
Somorjai, GA ;
Alivisatos, AP .
SCIENCE, 2004, 304 (5671) :711-714
[34]   Self-assembly of microporous manganese oxide octahedral molecular sieve hexagonal flakes into mesoporous hollow nanospheres [J].
Yuan, JK ;
Laubernds, K ;
Zhang, QH ;
Suib, SL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (17) :4966-4967