Ozone production rate and hydrocarbon reactivity in 5 urban areas: A cause of high ozone concentration in Houston

被引:131
作者
Kleinman, LI [1 ]
Daum, PH
Imre, D
Lee, YN
Nunnermacker, LJ
Springston, SR
Weinstein-Lloyd, J
Rudolph, J
机构
[1] Brookhaven Natl Lab, Dept Environm Sci, Div Atmospher Sci, Upton, NY 11973 USA
[2] SUNY Old Westbury, Dept Chem Phys, Old Westbury, NY 11568 USA
[3] York Univ, Dept Chem, N York, ON M3J 1P3, Canada
[4] York Univ, Ctr Atmospher Res, N York, ON M3J 1P3, Canada
关键词
D O I
10.1029/2001GL014569
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
[1] Observations of ozone (O-3) and O-3 precursors taken from aircraft flights over Houston, TX, Nashville, TN; New York, NY; Phoenix, AZ, and Philadelphia, PA show that high concentrations of reactive volatile organic compounds (VOCs) in the Houston atmosphere lead to calculated O-3 production rates that are 2 to 5 times higher than in the other 4 cities even though NOx concentrations are comparable. Within the Houston metropolitan area, concentrations of VOCs and O-3 production rates are highest in the Ship Channel region; the location of one of the largest petrochemical complexes in the world. As a consequence the concentration of O-3 in the Houston metropolitan area has recently exceeded 250 ppb, the highest value observed in the U. S within the past 5 years.
引用
收藏
页码:105 / 106
页数:4
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