Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

被引：476

作者：

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

DALTON TRANSACTIONS | 2009年 / 17期

基金：

加拿大自然科学与工程研究理事会;

关键词：

HETEROLYTIC DIHYDROGEN ACTIVATION; ORGANOCATALYTIC TRANSFER HYDROGENATION; METAL-FREE; AB-INITIO; BORANE; TRIPHENYLMETHYL; PHOSPHINES; REACTIVITY; REDUCTION; STEREOCHEMISTRY;

D O I：

10.1039/b819621d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The combination of Lewis acids and bases that are sterically precluded from forming Lewis acid-base adducts, termed Frustrated Lewis pairs provide a unique route to the activation of small molecules and applications in catalysis.

引用

页码：3129 / 3136

页数：8

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