Versatile, efficient derivatization of polysiloxanes via click technology

被引：49

作者：

Gonzaga, Ferdinand ^{[1
]}

Yu, Gilbert ^{[1
]}

Brook, Michael A. ^{[1
]}

机构：

[1] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 13期

关键词：

MODIFIED CARBOHYDRATE SURFACTANTS; HUISGEN 1,3-DIPOLAR CYCLOADDITION; SILOXANYL MOIETIES; CHEMISTRY APPROACH; AZIDES; ALKYNES; TETRAZOLES; LIGATION; SILICONE; SURFACES;

D O I：

10.1039/b821788b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper-catalyzed (click chemistry) or thermal 1,3-dipolar cycloadditions of molecular or polymeric azido-siloxanes with a broad range of alkynes (such as amino acids or carbohydrates) easily yield new conjugates that would be otherwise difficult, if not impossible, to prepare by traditional methodologies.

引用

页码：1730 / 1732

页数：3

共 32 条

[1] Peptidomimetics via copper-catalyzed azide-alkyne cycloadditions [J].

Angell, Yu L. ;

Burgess, Kevin .

CHEMICAL SOCIETY REVIEWS, 2007, 36 (10) :1674-1689

[2] Copper-free click chemistry for dynamic in vivo imaging [J].

Baskin, Jeremy M. ;

Prescher, Jennifer A. ;

Laughlin, Scott T. ;

Agard, Nicholas J. ;

Chang, Pamela V. ;

Miller, Isaac A. ;

Lo, Anderson ;

Codelli, Julian A. ;

Bertozzi, Carolyn R. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2007, 104 (43) :16793-16797

[3] 'Click' chemistry in polymer and material science: An update [J].

Binder, Wolfgang H. ;

Sachsenhofer, Robert .

MACROMOLECULAR RAPID COMMUNICATIONS, 2008, 29 (12-13) :952-981

[4] Organic azides:: An exploding diversity of a unique class of compounds [J].

Bräse, S ;

Gil, C ;

Knepper, K ;

Zimmermann, V .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (33) :5188-5240

[5]

BRAUNMUHL V, 1995, MACROMOLECULES, V28, P17

[6]

Brook M.A., 2000, SILICON ORGANIC ORGA, P256

[7] Silicone-protein interaction at the interface between a functional silicone and a protein/starch microparticle [J].

Brook, MA ;

Jiang, JX ;

Heritage, P ;

Bartzoka, V ;

Underdown, B ;

McDermott, MR .

LANGMUIR, 1997, 13 (23) :6279-6286

[8]

Demko ZP, 2002, ANGEW CHEM INT EDIT, V41, P2110, DOI 10.1002/1521-3773(20020617)41:12<2110::AID-ANIE2110>3.0.CO

[9]

2-7

[10]

Demko ZP, 2002, ANGEW CHEM INT EDIT, V41, P2113, DOI 10.1002/1521-3773(20020617)41:12<2113::AID-ANIE2113>3.0.CO

← 1 2 3 4 →