Gold-catalyzed intramolecular [3+2]-cycloaddition of arenyne-yne functionalities

被引：120

作者：

Lian, Jian-Jou ^{[1
]}

Chen, Po-Chiang ^{[1
]}

Lin, Yau-Ping ^{[1
]}

Ting, Hao-Chun ^{[1
]}

Liu, Rai-Shung ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu, Taiwan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 35期

关键词：

D O I：

10.1021/ja0643826

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a new efficient intramolecular [3 + 2]-cycloaddition of unactivated arenyne (or enyne)-yne functionalities, catalyzed mainly by the AuPPh3SbF6 complex (2 mol %) under ambient conditions. The value of this cyclization is reflected by its applicability to a wide range of diyne substrates bearing various functional groups. Copyright © 2006 American Chemical Society.

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页码：11372 / 11373

页数：2

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