ΛETN values for 1-methyl-2-pyrrolidinone -: Solvent binary mixtures at 20, 30, and 50 °C

被引：7

作者：

Kemell, M ^{[1
]}

Pirilä, P

机构：

[1] Univ Helsinki, Dept Chem, FIN-00014 Helsinki, Finland

[2] Oulu Univ, Dept Chem, FIN-90401 Oulu, Finland

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2000年 / 29卷 / 01期

关键词：

1-methyl-2-pyrrolidinone; binary solvent mixtures; solvent polarity; preferential solvation; synergetic effect;

D O I：

10.1023/A:1005118601769

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Delta E-T(N) values were determined for 8 1-methyl-2-pyrrolidinone-solvent mixtures over the whole mole fraction range at 20, 30, and 50 degrees C. The solvents used were acetone, dimethyl sulfoxide, 2-propanol, 1,2-dichloroethane, water, 1,4-dioxane, benzyl alcohol, and hexamethylphosphoric triamide. The Delta E-T(N) values were positive for the NMP + solvent systems, except for the NMP + water system.

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收藏

页码：87 / 99

页数：13

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