Synthesis and characterization of (R)-(+)-α-methylbenzylmethacryloylamine.: A novel and versatile monomer

被引:7
作者
Gutiérrez-Pérez, R
Percino, MJ
Chapela, VM
Alvarez, C
机构
[1] Univ Autonoma Puebla, Fac Ciencias Quim, Ctr Invest, Puebla 72001, Mexico
[2] Univ Autonoma Puebla, Inst Ciencias, Ctr Quim, Puebla 72000, Mexico
[3] Univ Nacl Autonoma Mexico, Inst Quim, Coyoacan 04510, DF, Mexico
关键词
(R)-(+)-alpha-methylbenzylmethacryloylamine; chiral monomer; NLO properties;
D O I
10.1163/156855599X00331
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We synthesized (R)-(+)-alpha-methylbenzylmethacryloylamine from the condensation reaction of methacryloyl chloride with (R)-(+)-alpha-methylbenzylamine in order to make a prototype molecule that can mimic some of the necessary characteristics of nonlinear optical (NLO) materials and that could also display potential chiral polymer catalyst properties. The structure of the new monomer (R)-(+)-alpha-methylbenzylmethacryloylamine along with the formation of the corresponding polymer was determined by NMR and IR spectroscopy.
引用
收藏
页码:103 / 107
页数:5
相关论文
共 8 条
[1]  
BELLAMY J, 1975, INFRARED SPECTRA COM, P231
[2]   TECHNOLOGY - HERESY IN THE WORLD OF ORGANIC NONLINEAR OPTICS [J].
BREDAS, JL ;
MEYERS, F .
NATURE, 1995, 375 (6530) :362-363
[3]   Chiral polymers via asymmetric epoxidation and asymmetric dihydroxylation [J].
Cernerud, M ;
Reina, JA ;
Tegenfeldt, J ;
Moberg, C .
TETRAHEDRON-ASYMMETRY, 1996, 7 (10) :2863-2870
[4]   ENANTIOSELECTIVE SYNTHESIS OF BETA-AMINO ACIDS .6. HIGH 1,2-STEREOINDUCTION IN THE PREPARATION OF ENANTIOPURE 2(R)-HYDROXY-3(R)-N-BENZOYLAMINO-3-PHENYLPROPIONIC ACID (LIKE STEREOISOMER OF TAXOLS SIDE-CHAIN) [J].
ESCALANTE, J ;
JUARISTI, E .
TETRAHEDRON LETTERS, 1995, 36 (25) :4397-4400
[5]   NONLINEAR OPTICS OF ORGANIC AND POLYMER MATERIALS [J].
GARITO, A ;
SHI, RF ;
WU, M .
PHYSICS TODAY, 1994, 47 (05) :51-57
[6]   NONLINEAR-OPTICAL POLYMERS - DISCOVERY TO MARKET IN 10 YEARS [J].
MARDER, SR ;
FERRY, JW .
SCIENCE, 1994, 263 (5154) :1706-1707
[7]  
PITTMAN CU, 1982, COMPREHENSIVE ORGANO, V8, P553
[8]  
WILLIAMS DH, 1980, SPECTROSCOPIC METHOD, P137