Li1+xV3O8 as a lithium insertion host

被引:4
作者
Kishi, T [1 ]
Kawakita, J [1 ]
Miura, T [1 ]
机构
[1] Keio Univ, Dept Appl Chem, Fac Sci & Technol, Kouhoku Ku, Yokohama, Kanagawa 2238522, Japan
关键词
vanadate; lithium; insertion;
D O I
10.5796/electrochemistry.68.2
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Lithium insertion behaviours of Li1+xV3O8 and its modified oxides were examined. Li4V3O8 phase was formed at x=1.5 in Li1+xV3O8 and had smaller insertion rate of lithium. Modification of VO5 unit in the layer and neighboring octahedral Li+ ions in the interlayer affected the formation of Li4V3O8 phase. Lattice disorder and layer stacking of the mother oxide also influenced the insertion behaviour of Li4V3O8 phase.
引用
收藏
页码:2 / 7
页数:6
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