Laboratory investigation of photochemical oxidation of organic aerosol from wood fires 2: analysis of aerosol mass spectrometer data

被引：141

作者：

Grieshop, A. P. ^{[1
]}

Donahue, N. M. ^{[1
]}

Robinson, A. L. ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Ctr Atmospher Particle Studies, Pittsburgh, PA 15213 USA

来源：

ATMOSPHERIC CHEMISTRY AND PHYSICS | 2009年 / 9卷 / 06期

关键词：

AIR-POLLUTION SOURCES; FINE-PARTICLE MASS; SOURCE APPORTIONMENT; HETEROGENEOUS OXIDATION; MOLECULAR MAKERS; HYDROCARBON-LIKE; DIESEL EXHAUST; EMISSIONS; SECONDARY; COMBUSTION;

D O I：

10.5194/acp-9-2227-2009

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Experiments were conducted to investigate the effects of photo-oxidation on organic aerosol (OA) in dilute wood smoke by exposing emissions from soft- and hardwood fires to UV light in a smog chamber. This paper focuses on changes in OA composition measured using a unit-mass-resolution quadrupole Aerosol Mass Spectrometer (AMS). The results highlight how photochemical processing can lead to considerable evolution of the mass, volatility and level of oxygenation of biomass-burning OA. Photochemical oxidation produced substantial new OA, more than doubling the OA mass after a few hours of aging under typical summertime conditions. Aging also decreased the volatility of the OA and made it progressively more oxygenated. The results also illustrate strengths of, and challenges with, using AMS data for source apportionment analysis. For example, the mass spectra of fresh and aged BBOA are distinct from fresh motor-vehicle emissions. The mass spectra of the secondary OA produced from aging wood smoke are very similar to those of the oxygenated OA (OOA) that dominates ambient AMS datasets, further reinforcing the connection between OOA and OA formed from photo-chemistry. In addition, aged wood smoke spectra are similar to those from OA created by photo-oxidizing dilute diesel exhaust. This demonstrates that the OOA observed in the atmosphere can be produced by photochemical aging of dilute emissions from different types of combustion systems operating on fuels with modern or fossil carbon. Since OOA is frequently the dominant component of ambient OA, the similarity of spectra of aged emissions from different sources represents an important challenge for AMS-based source apportionment studies.

引用

页码：2227 / 2240

页数：14

共 50 条

[11] Aging of biomass burning aerosols over West Africa: Aircraft measurements of chemical composition, microphysical properties, and emission ratios [J].

Capes, G. ;

Johnson, B. ;

McFiggans, G. ;

Williams, P. I. ;

Haywood, J. ;

Coe, H. .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2008, 113 (D20)

[12] Technical note: Description and use of the new jump mass spectrum mode of operation for the aerodyne quadrupole aerosol mass spectrometers (Q-AMS) [J].

Crosier, J. ;

Jimenez, J. L. ;

Allan, J. D. ;

Bower, K. N. ;

Williams, P. I. ;

Alfarra, M. R. ;

Canagaratna, M. R. ;

Jayne, J. T. ;

Worsnop, D. R. ;

Coe, H. .

AEROSOL SCIENCE AND TECHNOLOGY, 2007, 41 (09) :865-872

[13] Sources of particulate matter in the northeastern United States in summer: 1. Direct emissions and secondary formation of organic matter in urban plumes [J].

de Gouw, J. A. ;

Brock, C. A. ;

Atlas, E. L. ;

Bates, T. S. ;

Fehsenfeld, F. C. ;

Goldan, P. D. ;

Holloway, J. S. ;

Kuster, W. C. ;

Lerner, B. M. ;

Matthew, B. M. ;

Middlebrook, A. M. ;

Onasch, T. B. ;

Peltier, R. E. ;

Quinn, P. K. ;

Senff, C. J. ;

Stohl, A. ;

Sullivan, A. P. ;

Trainer, M. ;

Warneke, C. ;

Weber, R. J. ;

Williams, E. J. .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2008, 113 (D8)

[14] Budget of organic carbon in a polluted atmosphere: Results from the New England Air Quality Study in 2002 [J].

de Gouw, JA ;

Middlebrook, AM ;

Warneke, C ;

Goldan, PD ;

Kuster, WC ;

Roberts, JM ;

Fehsenfeld, FC ;

Worsnop, DR ;

Canagaratna, MR ;

Pszenny, AAP ;

Keene, WC ;

Marchewka, M ;

Bertman, SB ;

Bates, TS .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2005, 110 (D16) :1-22

[15] Fast airborne aerosol size and chemistry measurements above Mexico City and Central Mexico during the MILAGRO campaign [J].

DeCarlo, P. F. ;

Dunlea, E. J. ;

Kimmel, J. R. ;

Aiken, A. C. ;

Sueper, D. ;

Crounse, J. ;

Wennberg, P. O. ;

Emmons, L. ;

Shinozuka, Y. ;

Clarke, A. ;

Zhou, J. ;

Tomlinson, J. ;

Collins, D. R. ;

Knapp, D. ;

Weinheimer, A. J. ;

Montzka, D. D. ;

Campos, T. ;

Jimenez, J. L. .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2008, 8 (14) :4027-4048

[16] Laboratory investigation of photochemical oxidation of organic aerosol from wood fires 1: measurement and simulation of organic aerosol evolution [J].

Grieshop, A. P. ;

Logue, J. M. ;

Donahue, N. M. ;

Robinson, A. L. .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2009, 9 (04) :1263-1277

[17] Is the gas-particle partitioning in alpha-pinene secondary organic aerosol reversible? [J].

Grieshop, Andrew P. ;

Donahue, Neil M. ;

Robinson, Allen L. .

GEOPHYSICAL RESEARCH LETTERS, 2007, 34 (14)

[18]

GRIESHOP AP, 2009, ENV SCI TEC IN PRESS

[19] Correlation of secondary organic aerosol with odd oxygen in Mexico City [J].

Herndon, Scott C. ;

Onasch, Timothy B. ;

Wood, Ezra C. ;

Kroll, Jesse H. ;

Canagaratna, Manjula R. ;

Jayne, John T. ;

Zavala, Miguel A. ;

Knighton, W. Berk ;

Mazzoleni, Claudio ;

Dubey, Manvendra K. ;

Ulbrich, Ingrid M. ;

Jimenez, Jose L. ;

Seila, Robert ;

de Gouw, Joost A. ;

de Foy, Benjamin ;

Fast, Jerome ;

Molina, Luisa T. ;

Kolb, Charles E. ;

Worsnop, Douglas R. .

GEOPHYSICAL RESEARCH LETTERS, 2008, 35 (15)

[20] Diel and seasonal variations in the chemical composition of biomass burning aerosol [J].

Hoffer, A. ;

Gelencser, A. ;

Blazso, M. ;

Guyon, P. ;

Artaxo, P. ;

Andreae, M. O. .

ATMOSPHERIC CHEMISTRY AND PHYSICS, 2006, 6 :3505-3515

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