XRD evaluation of KOH activation process and influence of coal rank

被引:114
作者
Yoshizawa, N
Maruyama, K
Yamada, Y
Ishikawa, E
Kobayashi, M
Toda, Y
Shiraishi, M
机构
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058569, Japan
[2] Tokai Univ, Shizuoka 4100395, Japan
关键词
KOH activation; X-ray diffraction; coal rank;
D O I
10.1016/S0016-2361(02)00101-1
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Three Japanese coals with different rank (Ohmine, Miike and Taiheiyo coals) were activated with KOH from 300 to 850 degreesC. Higher rank coal with lower oxygen content showed a high yield and also a large specific surface area determined by N-2 adsorption isotherms. X-ray diffraction (XRD) patterns of the activated carbons were measured to characterize stacking structure of aromatic layers by standardized analysis of coal by XRD method, considering the presence of slit-shaped micropores among the stacking structure. Structural parameters obtained by this method were related to the yield and the surface area in order to discuss the feature of micropores developed during the activation. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1717 / 1722
页数:6
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