Synthesis, crystal structure, and characterization of layered aluminum methylphosphonate

被引：31

作者：

Maeda, K

Hashiguchi, Y

Kiyozumi, Y

Mizukami, F

机构：

[1] Natl. Inst. of Mat. and Chem. Res., Tsukuba, Ibaraki 305

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1997年 / 70卷 / 02期

关键词：

D O I：

10.1246/bcsj.70.345

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first aluminum methylphosphonate with a layered structure, designated AlMepO-zeta, giving an ideal composition of Al(OH)(O3PCH3). H2O was synthesized with a hydrothermal procedure. AlMepO-zeta is monoclinic, space group P2(1)/c, with a = 7.8676(7), b = 7.0744(13), c = 9.4789(7), beta = 106.599(6)degrees. The framework in a sheet containing unidimensional [-Al-(OH)-Al-] chain is topologically the same as VO(O3PC6H5). H2O. Methyl groups protrude into the interlamellar space. TG-DTA and MAS-NMR results revealed the decomposition mechanism.

引用

收藏

页码：345 / 349

页数：5

相关论文

共 27 条

[1] SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF A NEW LAMELLAR IRON PHOSPHONATE, FEII(C2H5PO3).H2O [J].

BUJOLI, B ;

PENA, O ;

PALVADEAU, P ;

LEBIDEAU, J ;

PAYEN, C ;

ROUXEL, J .

CHEMISTRY OF MATERIALS, 1993, 5 (04) :583-587

[2] SYNTHESIS OF NEW LAMELLAR IRON(III) PHOSPHONATES [J].

BUJOLI, B ;

PALVADEAU, P ;

ROUXEL, J .

CHEMISTRY OF MATERIALS, 1990, 2 (05) :582-589

[3] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF LAYERED CALCIUM AND LANTHANIDE PHOSPHONATE SALTS [J].

CAO, G ;

LYNCH, VM ;

SWINNEA, JS ;

MALLOUK, TE .

INORGANIC CHEMISTRY, 1990, 29 (11) :2112-2117

[4] SHAPE-SELECTIVE INTERCALATION REACTIONS OF LAYERED ZINC AND COBALT PHOSPHONATES [J].

CAO, G ;

MALLOUK, TE .

INORGANIC CHEMISTRY, 1991, 30 (07) :1434-1438

[5] SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND INTERCALATION CHEMISTRY OF 2 LAYERED CADMIUM ORGANOPHOSPHONATES [J].

CAO, G ;

LYNCH, VM ;

YACULLO, LN .

CHEMISTRY OF MATERIALS, 1993, 5 (07) :1000-1006

[6] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A HOMOLOGOUS SERIES OF DIVALENT-METAL PHOSPHONATES, MII(O3PR).H2O AND MII(HO3PR)2 [J].

CAO, G ;

LEE, H ;

LYNCH, VM ;

MALLOUK, TE .

INORGANIC CHEMISTRY, 1988, 27 (16) :2781-2785

[7] LAYERED METAL PHOSPHATES AND PHOSPHONATES - FROM CRYSTALS TO MONOLAYERS [J].

CAO, G ;

HONG, HG ;

MALLOUK, TE .

ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (09) :420-427

[8]

CARTER VJ, IN PRESS J CHEM S DA

[9] CRYSTALLOGRAPHY AND STRUCTURE OF ALPHA-ZIRCONIUM BIS(MONOHYDROGEN ORTHOPHOSPHATE) MONOHYDRATE [J].

CLEARFIELD, A ;

SMITH, GD .

INORGANIC CHEMISTRY, 1969, 8 (03) :431-+

[10] HYDROTHERMAL SYNTHESIS AND SINGLE-CRYSTAL STRUCTURAL CHARACTERIZATION OF THE LAYERED VANADIUM(IV) PHOSPHATE VOC6H5PO3.H2O [J].

HUAN, GH ;

JACOBSON, AJ ;

JOHNSON, JW ;

CORCORAN, EW .

CHEMISTRY OF MATERIALS, 1990, 2 (02) :91-93