Synthesis, crystal structure, and characterization of layered aluminum methylphosphonate

被引：31

作者：

Maeda, K

Hashiguchi, Y

Kiyozumi, Y

Mizukami, F

机构：

[1] Natl. Inst. of Mat. and Chem. Res., Tsukuba, Ibaraki 305

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1997年 / 70卷 / 02期

关键词：

D O I：

10.1246/bcsj.70.345

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first aluminum methylphosphonate with a layered structure, designated AlMepO-zeta, giving an ideal composition of Al(OH)(O3PCH3). H2O was synthesized with a hydrothermal procedure. AlMepO-zeta is monoclinic, space group P2(1)/c, with a = 7.8676(7), b = 7.0744(13), c = 9.4789(7), beta = 106.599(6)degrees. The framework in a sheet containing unidimensional [-Al-(OH)-Al-] chain is topologically the same as VO(O3PC6H5). H2O. Methyl groups protrude into the interlamellar space. TG-DTA and MAS-NMR results revealed the decomposition mechanism.

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页码：345 / 349

页数：5

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