Simultaneous ejection of six electrons at a constant potential by hexakis(4-ferrocenylphenyl) benzene

被引：69

作者：

Chebny, Vincent J. ^{[1
]}

Dhar, Dwairath ^{[1
]}

Lindeman, Sergey V. ^{[1
]}

Rathore, Rajendra ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Milwaukee, WI 53201 USA

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 22期

关键词：

D O I：

10.1021/ol061904d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple synthesis of a dendritic hexaferrocenyl electron donor (5) is described in which six ferrocene moieties are connected at the vertices of the propeller of the hexaphenylbenzene core. The molecular structure of 5 is confirmed by X-ray crystallography. An electrochemical analysis along with redox titrations (which are tantamount to coulometry) confirmed that it ejects six electrons at a single potential.

引用

页码：5041 / 5044

页数：4

共 23 条

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