Very high rate enhancement of benzyl alcohol oxidation by an artificial enzyme

被引：76

作者：

Marinescu, Lavinia G. ^{[1
]}

Bols, Mikael ^{[1
]}

机构：

[1] Aarhus Univ, Dept Chem, DK-8000 Aarhus, Denmark

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 28期

关键词：

biomimetics; cyclodextrins; Michaelis-Menten kinetics; supramolecular chemistry;

D O I：

10.1002/anie.200600812

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Promoting the atomic dialogue! At neutral pH and ambient temperature, a cyclodextrin-derived ketone causes hydrogen peroxide and benzyl alcohols to meet in its active site and react up to 60 000 times faster than they do outside the cyclodextrin. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4590 / 4593

页数：4

共 24 条

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SASAKI S, 1992, STUDIES ORGANIC CHEM, V45, P265

[22] HIGH ACYLATION RATES AND ENANTIOSELECTIVITY WITH CYCLODEXTRIN COMPLEXES OF RIGID SUBSTRATES [J].