High yield thiolation of iodobenzene catalyzed by the phosphinite nickel PCP pincer complex:: [NiCl{C6H3-2,6-(OPPh2)2}]

被引：160

作者：

Gomez-Benitez, Valente ^{[1
]}

Baldovino-Pantaleon, Oscar ^{[1
]}

Herrera-Alvarez, Cesar ^{[1
]}

Toscano, Ruben A. ^{[1
]}

Morales-Morales, David ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 29期

关键词：

C-S cross-coupling; phosphinite ligands; homogeneous catalysis; nickel; pincer complexes; thiolation;

D O I：

10.1016/j.tetlet.2006.05.094

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

NiCl (C6H3-2,6-(OPPh2)(2))] efficiently catalyzes the thiolation of iodobenzene with a broad scope of disulfides in the presence of zinc, the coupled products are obtained in excellent and in many cases nearly quantitative yields. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：5059 / 5062

页数：4

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