Fischer-Tropsch catalysis: The basis for an emerging industry with origins in the early 20th Century

被引:53
作者
Casci, John L. [1 ]
Lok, C. Martin [1 ]
Shannon, Mervyn D. [2 ,3 ]
机构
[1] Johnson Matthey Technol Ctr, Billingham TS23 1LB, Cleveland, England
[2] Wilton Ctr, Redcar TS10 4RF, Cleveland, England
[3] CLRC Daresbury Labs, UK SuperSTEM Facil, Warrington WA4 4AD, Cheshire, England
关键词
Fischer-Tropsch catalysis; Industrial catalysis; Catalyst characterisation; COBALT CATALYSTS; SUPPORT;
D O I
10.1016/j.cattod.2008.08.032
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Fischer-Tropsch catalysts, based on cobalt, are complex materials containing the catalyst support and reduction and structural promoters in addition to the cobalt metal itself. While this basic description covers both modern FT catalyst and those first commercialised, in Germany in 1930s, modern FT catalysts have vastly improved performance. While such improvements owe much to modern materials and manufacturing methods, the role of advanced characterisation techniques cannot be underestimated. Modern techniques discern details of catalyst structure that were not available during the early pioneering work, they guide current developments and offer the prospect of designing tailored catalysts. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:38 / 44
页数:7
相关论文
共 33 条
[1]  
[Anonymous], 1924, BRENNST CHEM
[2]   Toward three-dimensional nanoengineering of heterogeneous catalysts [J].
Arslan, Ilke ;
Walmsley, John C. ;
Rytter, Erling ;
Bergene, Edvard ;
Midgley, Paul A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (17) :5716-5719
[3]  
Bartholomew C. H., 2003, AICHE SPRING M NEW O
[4]  
BASF, 1914, Patent No. 295202
[5]  
BASF, 1913, German Patent, Patent No. [293787, 293,787]
[6]  
BASF, 1914, Patent No. 295203
[7]   Sub-angstrom resolution using aberration corrected electron optics [J].
Batson, PE ;
Dellby, N ;
Krivanek, OL .
NATURE, 2002, 418 (6898) :617-620
[8]   Investigation of promoter effects of manganese oxide on carbon nanofiber-supported cobalt catalysts for Fischer-Tropsch synthesis [J].
Bezemer, GL ;
Radstake, PB ;
Falke, U ;
Oosterbeek, H ;
Kuipers, HPCE ;
van Dillen, A ;
de Jong, KP .
JOURNAL OF CATALYSIS, 2006, 237 (01) :152-161
[9]  
Bonne RLC, 1999, US Patent, Patent No. [5,874,381, 5874381]
[10]  
*BRIT INT OBJ SUB, 1946, 447 BIOS