The non-covalent assembly of benzene-bridged metallosalphen dimers: photoconductive tapes with large carrier mobility and spatially distinctive conduction anisotropy

被引：9

作者：

Chen, Long ^{[2
]}

Wang, Lu ^{[3
]}

Gao, Xingfa ^{[3
]}

Nagase, Shigeru ^{[3
]}

Honsho, Yoshihito ^{[1
]}

Saeki, Akinori ^{[1
]}

Seki, Shu ^{[1
,4
]}

Jiang, Donglin ^{[2
,4
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Inst Mol Sci, Dept Mat Mol Sci, Okazaki, Aichi 4478787, Japan

[3] Inst Mol Sci, Dept Theoret & Computat Mol Sci, Okazaki, Aichi 4448585, Japan

[4] Japan Sci & Technol Agcy, JST, Precursory Res Embryon Sci & Technol PRESTO, Chiyoda Ku, Tokyo 1020075, Japan

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 21期

关键词：

ELECTRON-TRANSFER; CHARGE-CARRIERS; NANOTUBES; TRANSPORT; POLYMERS; COMPLEX; DONOR;

D O I：

10.1039/b904337c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A newly synthesized benzene-bridged metallosalphen dimer tailored with aliphatic chains is demonstrated for the solution-processed assembly of a pi-electronic tape, which shows a large intrinsic carrier mobility, is spatially anisotropic in conduction, forms p- or n-type semiconductors tunable upon doping, is photoconductive and is capable of repetitive switching with large on-off ratios.

引用

页码：3119 / 3121

页数：3

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