Synthesis of the (17R)- and (17S)-isomers of volicitin, an elicitor of plant volatiles contained in the oral secretion of the beet armyworm

被引：15

作者：

Itoh, S

Kuwahara, S

Hasegawa, M

Kodama, O

机构：

[1] Tohoku Univ, Grad Sch Agr Sci, Div Life Sci, Lab Appl Bioorgan Chem,Aoba Ku, Sendai, Miyagi 9818555, Japan

[2] Ibaraki Univ, Fac Agr, Lab Agr Chem, Ibaraki 3000393, Japan

来源：

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 2002年 / 66卷 / 07期

关键词：

volicitin; elicitor; Spodoptera exigua; 17-hydroxylinolenic acid;

D O I：

10.1271/bbb.66.1591

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Both the (17R)- and (17S)-isomers of volicitin, which is contained in the oral secretion of the beet armyworm and induces corn seedlings to emit a blend of volatile compounds to attract the natural enemy of the herbivore, were synthesized via the semi-hydrogenation of an intermediary diyne and (Z)-selective olefination as the key steps. They were both obtained as crystalline compounds.

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页码：1591 / 1596

页数：6

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