Enantioselective deprotonation reactions using a novel homochiral magnesium amide base

被引：52

作者：

Henderson, KW ^{[1
]}

Kerr, WJ ^{[1
]}

Moir, JH ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 06期

关键词：

D O I：

10.1039/b000425l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel homochiral magnesium bisamide base system has been prepared and reacted with a series of prochiral ketones in the presence of TMSCl to give efficient formation of the corresponding enol ethers in enantiomeric ratios of up to 95:5.

引用

页码：479 / 480

页数：2

共 20 条

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