Synthesis of silicon carbide whiskers from substituted silicon alkoxides and rayon fibres

被引:7
作者
Raman, V [1 ]
Parashar, VK [1 ]
Dhakate, SR [1 ]
机构
[1] Natl Phys Lab, Engn Mat Div, Carbon Technol Unit, New Delhi 110012, India
关键词
silicon carbide whiskers; sol-gel; substituted silicon alkoxides; rayon fibres; carbothermal reduction;
D O I
10.1023/A:1019984918105
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Silicon carbide whiskers (SiCW) were synthesized through sol-gel process by impregnating the rayon fibres with sols of methyltriethoxysilane (MTEOS), phenyltriethoxysilane (PTEOS) and dimethyldiethoxysilane (DMDEOS) and pyrolyzing the impregnated rayon fibres at 1400degreesC in argon atmosphere. The SiCW synthesized through this method were needle like, straight and their aspect ratio was found to be greater than 100 except in the case where DMDEOS was used as silica source.
引用
收藏
页码:175 / 179
页数:5
相关论文
共 24 条
[1]   Effect of contact area on synthesis of silicon carbide through carbothermal reduction of silicon dioxide [J].
Chen, SH ;
Lin, CI .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1997, 16 (09) :702-704
[2]  
CHIU JM, 1990, J MATER SCI, V25, P2583
[3]  
Dai CH, 1997, J AM CERAM SOC, V80, P1274
[4]   SYNTHESIS OF MONODISPERSED SPHERICAL BETA-SILICON CARBIDE POWDER BY A SOL-GEL PROCESS [J].
HATAKEYAMA, F ;
KANZAKI, S .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1990, 73 (07) :2107-2110
[5]   DIRECT PYROLYSIS OF RAW RICE HUSKS FOR MAXIMIZATION OF SILICON-CARBIDE WHISKER FORMATION [J].
KRISHNARAO, RV ;
GODKHINDI, MM ;
MUKUNDA, PGI ;
CHAKRABORTY, M .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (11) :2869-2875
[6]   FORMATION OF SIC WHISKERS FROM RICE HUSK SILICA CARBON-BLACK MIXTURE - EFFECT OF PREHEAT TREATMENT [J].
KRISHNARAO, RV .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1993, 12 (16) :1268-1271
[7]   Synthesis of nanometre silicon carbide whiskers from binary carbonaceous silica aerogels [J].
Li, XK ;
Liu, L ;
Zhang, YX ;
Shen, SD ;
Ge, S ;
Ling, LC .
CARBON, 2001, 39 (02) :159-165
[8]   Control of the composition and structure of silicon oxycarbide and oxynitride glasses derived from polysiloxane precursors [J].
Mutin, PH .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1999, 14 (01) :27-38
[9]   HIGH-TEMPERATURE TOUGHNESS AND TENSILE-STRENGTH OF WHISKER-REINFORCED SILICON-NITRIDE [J].
OHJI, T ;
GOTO, Y ;
TSUGE, A .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1991, 74 (04) :739-745
[10]   Influence of boric acid on the synthesis of silicon carbide whiskers from rice husks and polyacrylonitrile [J].
Raman, V ;
Parashar, VK ;
Bahl, OP .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1997, 16 (15) :1252-1254