Ammonium oxofluorotitanates

被引：67

作者：

Laptash, NM ^{[1
]}

Maslennikova, IG ^{[1
]}

Kaidalova, TA ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Chem, Far Eastern Branch, Vladivostok 690022, Russia

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1999年 / 99卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

ammonium hexafluorotitanate; hydrolysis; oxofluorotitanates; IR spectra;

D O I：

10.1016/S0022-1139(99)00136-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By hydrolysis of (NH4)(2)TiF6 ammonium oxofluorotitanates (NH4)(3)TiOF5, (NH4)(2)TiOF4, and NH4TiOF3 were obtained and characterized, (NH4)(3)TiOF5 has been synthesized for the first time. New derivatives from NH4TiOF3 with lower content of ammonium and fluorine are described. It was established that the titanium fluorocompound assumed as NH4TiF5 should be considered as a volatile oxofluorocomplex. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：133 / 137

页数：5

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