Improving the Hydrogen-Adsorption Properties of a Hydroxy-Modified MIL-53(Al) Structural Analogue by Lithium Doping

被引：187

作者：

Himsl, Dieter ^{[1
]}

Wallacher, Dirk ^{[2
]}

Hartmann, Martin ^{[1
]}

机构：

[1] Univ Augsburg, Inst Phys, D-86159 Augsburg, Germany

[2] Helmholtz Zentrum Mat & Energie GmbH, D-14109 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 25期

关键词：

adsorption; doping; hydrogen; lithium; microporous materials; METAL-ORGANIC FRAMEWORKS; HETEROGENEOUS ASYMMETRIC CATALYSIS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; MAGNETIC-PROPERTIES; STORAGE CAPACITY; SALICYLIC-ACID; SURFACE-AREA; H-2; STORAGE; FUNCTIONALIZATION;

D O I：

10.1002/anie.200806203

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lithium makes the difference: A simple strategy for the synthesis of lithium-doped porous metal-organic frameworks (MOFs) is developed (see structure; C black, O red, AlO6 blue octahedra), thus paving the way for the facile preparation of lithium-doped MOFs. Moreover, the significant increase in hydrogen adsorption predicted by theoretical calculations is observed. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4639 / 4642

页数：4

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