Switchable nonlinear optical metallochromophores with pyridinium electron acceptor groups

被引：402

作者：

Coe, Benjamin J. ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2006年 / 39卷 / 06期

关键词：

D O I：

10.1021/ar050225k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organotransition metal complexes have much to offer as nonlinear optical (NLO) chromophores since they allow large hyperpolarizabilities to be combined with various other physical properties in an unparalleled diversity of molecular structures. This Account summarizes our synthetic chemistry driven investigations in the NLO research field, which have focused primarily on complexes of ruthenium, and to some extent iron. A number of fascinating discoveries are described, including the first demonstration of redox-induced switching of NLO behavior and chromophores which disobey the otherwise universal rule that elongation of polyene systems leads to continual increases in quadratic NLO responses.

引用

页码：383 / 393

页数：11

共 53 条

[11]

Coe BJ, 2002, J PHYS CHEM A, V106, P897, DOI [10.1021/jp012320q, 10.1021/jp0123210q]

[12] Syntheses and properties of two-dimensional charged nonlinear optical chromophores incorporating redox-switchable cis-tetraammineruthenium(II) centers [J].

Coe, BJ ;

Harris, JA ;

Jones, LA ;

Brunschwig, BS ;

Song, K ;

Clays, K ;

Garín, J ;

Orduna, J ;

Coles, SJ ;

Hursthouse, MB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (13) :4845-4859

[13]

Coe BJ, 1999, ANGEW CHEM INT EDIT, V38, P366, DOI 10.1002/(SICI)1521-3773(19990201)38:3<366::AID-ANIE366>3.0.CO

[14]

2-D

[15]

Coe BJ, 2002, ADV FUNCT MATER, V12, P110, DOI 10.1002/1616-3028(20020201)12:2<110::AID-ADFM110>3.0.CO

[16]

2-Y

[17] Syntheses and spectroscopic and quadratic nonlinear optical properties of extended dipolar complexes with ruthenium(II) ammine electron donor and N-methylpyridinium acceptor groups [J].

Coe, BJ ;

Jones, LA ;

Harris, JA ;

Brunschwig, BS ;

Asselberghs, I ;

Clays, K ;

Persoons, A ;

Garín, J ;

Orduna, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (12) :3880-3891

[18] Metal complexes for molecular electronics and photonics [J].

Coe, BJ ;

Curati, NRM .

COMMENTS ON INORGANIC CHEMISTRY, 2004, 25 (5-6) :147-184

[19] Three-dimensional non linear optical chromophores based on metal-to-ligand charge-transfer from ruthenium(II) or iron(II) centers [J].

Coe, BJ ;

Harris, JA ;

Brunschwig, BS ;

Asselberghs, I ;

Clays, K ;

Garín, J ;

Orduna, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (38) :13399-13410

[20] Large molecular quadratic hyperpolarizabilities in donor/acceptor-substituted trans-tetraammineruthenium(II) complexes [J].

Coe, BJ ;

Chamberlain, MC ;

EssexLopresti, JP ;

Gaines, S ;

Jeffery, JC ;

Houbrechts, S ;

Persoons, A .

INORGANIC CHEMISTRY, 1997, 36 (15) :3284-3292

← 1 2 3 4 5 6 →