Self-assembly of 2D Borromean networks through hydrogen-bonding recognition

被引:56
作者
Jang, Ji-Jun [1 ,2 ]
Li, Lei [1 ,2 ]
Yang, Tao [1 ,2 ]
Kuang, Dai-Bin [1 ,2 ]
Wang, Wei [3 ]
Su, Cheng-Yong [1 ,2 ]
机构
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China
[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Guangdong, Peoples R China
[3] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
关键词
SHOWING STRUCTURAL DIVERSITY; TOPOLOGY; CRYSTAL; INTERLOCKING;
D O I
10.1039/b820831j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Assembly of a tripodal ligand tris(2-benzimidazoylmethyl) amine with the long rod-like spacer N-1,N-4-bis(pyridin-4-ylmethylene)-benzene-1,4-diamine in the presence of M(ClO4)(2) (M = Cd2+ and Mn2+) or H3O center dot ClO4 leads to formation of 6(3)-hcb layers which interweave in a parallel fashion to give the first examples of hydrogen-bonding Borromean links.
引用
收藏
页码:2387 / 2389
页数:3
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