First-examples of metal and ligand accelerated catalysis of the Baylis-Hillman reaction

被引：60

作者：

Aggarwal, VK ^{[1
]}

Tarver, GJ ^{[1
]}

McCague, R ^{[1
]}

机构：

[1] CHIROSCI LTD,CAMBRIDGE CB4 4WE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 24期

关键词：

D O I：

10.1039/cc9960002713

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lanthanides and group III metal triflates (especially La, Sm) accelerate the Baylis-Hillman reaction (reaction between an unsaturated ester and aldehyde catalysed by DABCO, for example) and further acceleration can be obtained upon addition of diol ligands such as binol.

引用

页码：2713 / 2714

页数：2

共 15 条

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