Routes to regioselective deuteriation of heteroaromatic compounds

被引：40

作者：

Browne, WR

O'Connor, CM

Killeen, JS

Guckian, AL

Burke, M

James, P

Burke, M

Vos, JG ^{[1
]}

机构：

[1] Dublin City Univ, Sch Chem Sci, Natl Ctr Sensor Res, Dublin 9, Ireland

[2] Dublin Inst Technol, Dept Chem, Dublin 2, Ireland

[3] Dublin City Univ, Natl Inst Cellular Biotechnol, Dublin 9, Ireland

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 16期

关键词：

D O I：

10.1021/ic020226y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A systematic approach to the deuteriation of polypyridyl type ligands is reported. A range of isotopologues of heteroaromatic compounds containing pyrazyl, pyridyl, 1,2,4-triazole, thienyl, methyl, and phenyl moieties, have been prepared in a cost-effective manner, using a range of methods based on subcritical aqueous media. Selectively and fully deuteriated ligands are characterized by mass spectrometry and H-1, D-2, and C-13 NMR spectroscopy. The application of deuteriation to supramolecular chemistry is discussed.

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页码：4245 / 4251

页数：7

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