Asymmetric synthesis of tetrahydrofurans by competitive [1,2]-phenylsulfanyl (PhS) migrations under thermodynamic control

被引：7

作者：

Caggiano, L

Fox, DJ

House, D

Jones, ZA

Kerr, F

Warren, S

机构：

[1] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England

[2] Univ Milan, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy

[3] Dyson Perrins Lab, Oxford 0X1 3QY, England

[4] AstraZeneca, Macclesfield SK10 2NA, Cheshire, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2002年 / 23期

关键词：

D O I：

10.1039/b208556a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Triols were prepared in enantiomerically enriched form by a short route that included a Sharpless asymmetric dihydroxylation; treatment of these triols with toluene-p-sulfonic acid gave THFs as thermodynamic products.

引用

页码：2634 / 2645

页数：12

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