Production of zigzag-type BN nanotubes and BN cones by thermal annealing

被引:111
作者
Terauchi, M
Tanaka, M
Suzuki, K
Ogino, A
Kimura, K
机构
[1] Tohoku Univ, Sci Measurements Res Inst, Aoba Ku, Sendai, Miyagi 9808577, Japan
[2] Univ Tokyo, Dept Adv Mat Sci, Bunkyo Ku, Tokyo 1130033, Japan
关键词
D O I
10.1016/S0009-2614(00)00637-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Boron nitride nanotubes (BNT) and boron nitride cones (BN cones) were produced by thermal annealing of a mixed powder of beta-rhombohedral boron and hexagonal boron nitride (h-BN) at 1200 degrees C under lithium vapor. The BNTs were found to grow from the edge of h-BN particles along one of [10 (1) over bar 0] directions of the particles. The BNTs consist of zigzag-type layers whose [10 (1) over bar 0] direction is parallel to the tube axis. The BN cones with an apex angle of about 20 degrees were discovered. It was revealed that the BN cones were not formed by a helically wound conical BN layer but by a pile of monolayer BN cones. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:359 / 364
页数:6
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