Comparative behavior of polybutadiene and polynorbornene-based latices prepared by dispersion ring-opening metathesis polymerization with a poly(ethylene oxide) macromonomer

被引：13

作者：

Chemtob, A ^{[1
]}

Héroguez, V ^{[1
]}

Gnanou, Y ^{[1
]}

机构：

[1] Univ Bordeaux 1, CNRS, ENSCPB, UMR,Lab Chim Polymeres Organ, F-33607 Pessac, France

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2004年 / 42卷 / 11期

关键词：

dispersions; ROMP; ring-opening metathesis polymerization; colloidal stability; polybutadiene; 1,5-cyclooctadiene; polynorbornene; norbornene; macromonomers; particles;

D O I：

10.1002/pola.20141

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This study critically examines the similarities and differences between poly(ethylene oxide) (PEO) stabilized latices of polynorbornene and polybutadiene. Features such as the kinetics of copolymerization of norbornene and cyclooctadiene with a macromonomer of PEO, the particles' size and morphology, the type of copolymer formed, and the stability of these latices were investigated and the results obtained are considered. (C) 2004 Wiley Periodicals, Inc.

引用

页码：2705 / 2716

页数：12

共 23 条

[1]

Asua JM, 1998, ACTA POLYM, V49, P671, DOI 10.1002/(SICI)1521-4044(199812)49:12<671::AID-APOL671>3.0.CO

[2]

2-L

[3] A NOVEL HIGH-TEMPERATURE NONAQUEOUS DISPERSION POLYMERIZATION ROUTE TO FULLY AROMATIC MAIN-CHAIN LIQUID-CRYSTAL POLYMERS [J].

BUNN, A ;

GRIFFIN, BP ;

MACDONALD, WA ;

RANCE, DG .

POLYMER, 1992, 33 (14) :3066-3072

[4] Dispersion ring-opening metathesis polymerization of norbornene using PEO-based stabilizers [J].

Chemtob, A ;

Héroguez, V ;

Gnanou, Y .

MACROMOLECULES, 2002, 35 (25) :9262-9269

[5] Synthesis of polybutadiene-based particles via dispersion ring-opening metathesis polymerization [J].

Chemtob, A ;

Héroguez, V ;

Gnanou, Y .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (05) :1154-1163

[6] RUTHENIUM-CATALYZED RING-OPENING METATHESIS POLYMERIZATION OF CYCLOOLEFINS INITIATED BY DIAZOESTERS [J].

DEMONCEAU, A ;

NOELS, AF ;

SAIVE, E ;

HUBERT, AJ .

JOURNAL OF MOLECULAR CATALYSIS, 1992, 76 (1-3) :123-132

[7] SYNTHESIS OF GLYCOPOLYMERS OF CONTROLLED MOLECULAR-WEIGHT BY RING-OPENING METATHESIS POLYMERIZATION USING WELL-DEFINED FUNCTIONAL-GROUP TOLERANT RUTHENIUM CARBENE CATALYSTS [J].

FRASER, C ;

GRUBBS, RH .

MACROMOLECULES, 1995, 28 (21) :7248-7255

[8]

Héroguez V, 2000, MACROMOL SYMP, V150, P269, DOI 10.1002/1521-3900(200002)150:1<269::AID-MASY269>3.0.CO

[9]

2-I

[10] Synthesis of alpha-norbornenylpoly(ethylene oxide) macromonomers and their ring-opening metathesis polymerization [J].

Heroguez, V ;

Breunig, S ;

Gnanou, Y ;

Fontanille, M .

MACROMOLECULES, 1996, 29 (13) :4459-4464

← 1 2 3 →