RUTHENIUM-CATALYZED RING-OPENING METATHESIS POLYMERIZATION OF CYCLOOLEFINS INITIATED BY DIAZOESTERS

被引：106

作者：

DEMONCEAU, A

NOELS, AF

SAIVE, E

HUBERT, AJ

机构：

[1] UNIV LIEGE,MACROMOLEC CHEM & ORGAN CATALYSIS LAB,SART TILMAN B6,B-4000 LIEGE,BELGIUM

[2] UNIV LIEGE,ORGAN SYNTH & CATALYSIS,B-4000 LIEGE,BELGIUM

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 76卷 / 1-3期

关键词：

D O I：

10.1016/0304-5102(92)80151-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Addition of catalytic amounts of diazoesters to various ruthenium complexes, including some diruthenium(II,II) tetrakis carboxylates, led to new catalyst systems that promoted the ROMP not only of norbornene (bicyclo[2.2.1]heptene) but also of cyclooctene and cyclopentene. The conversion and the cis content of the polymers varied widely and depended on the nature of the catalyst precursor.

引用

页码：123 / 132

页数：10

共 37 条

[1] SYNTHESIS, SPECTRAL CHARACTERIZATION, AND ALKYLIDENE TRANSFER-REACTIONS OF ELECTROPHILIC IRON CARBENE COMPLEXES CP(CO)(L)FE=CHR+,L=CO,P(C6H5)3,R=CH3,CH2CH3,CH(CH3)2
BROOKHART, M
TUCKER, JR
HUSK, GR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (02) : 258 - 264
[2] Brown F. J., 1980, PROG INORG CHEM, V27, P1
[3] REACTIONS OF (DIPHENYLCARBENE)PENTACARBONYLTUNGSTEN(O) WITH ALKENES - ROLE OF METAL-CARBENE COMPLEXES IN CYCLOPROPANATION AND OLEFIN METATHESIS REACTIONS
CASEY, CP
BURKHARDT, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (25) : 7808 - 7809
[4] CHEMISTRY, STRUCTURE, AND BONDING IN DIRUTHENIUM(II) TETRACARBOXYLATES
COTTON, FA
MISKOWSKI, VM
ZHONG, BX
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (16) : 6177 - 6182
[5] EFFECTS OF SECONDARY INTERACTIONS ON THE STEREOCHEMICAL OUTCOME OF RHODIUM(II) CARBOXYLATE CATALYZED CYCLOPROPANATION OF OLEFINS
DEMONCEAU, A
NOELS, AF
HUBERT, AJ
[J]. TETRAHEDRON, 1990, 46 (11) : 3889 - 3896
[6] DEMONCEAU A, UNPUB
[7] GENERATION OF TRANSITION-METAL CARBENE COMPLEXES AND THEIR RELATIVE ACTIVITY IN CHAIN PROCESSES OF CYCLO-OLEFIN RING-OPENING POLYMERIZATION AND OLEFIN METATHESIS
DOLGOPLOSK, BA
ORESHKIN, IA
SMIRNOV, SA
KOPIEVA, IA
TINYAKOVA, EI
[J]. EUROPEAN POLYMER JOURNAL, 1979, 15 (03) : 237 - 240
[8] DOLGOPLOSK BA, 1974, DOKL AKAD NAUK, V216, P380
[9] Dotz K.H., 1983, TRANSITION METAL CAR
[10] CATALYTIC METHODS FOR METAL CARBENE TRANSFORMATIONS
DOYLE, MP
[J]. CHEMICAL REVIEWS, 1986, 86 (05) : 919 - 939

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