Synthesis of C60 intercalated graphite

被引：48

作者：

Gupta, V

Scharff, P

Risch, K

Romanus, H

Müller, R

机构：

[1] Tech Univ Ilmenau, Dept Phys, D-98684 Ilmenau, Germany

[2] Tech Univ Ilmenau, Dept Mat Sci, D-98684 Ilmenau, Germany

来源：

SOLID STATE COMMUNICATIONS | 2004年 / 131卷 / 3-4期

关键词：

fullerenes; chemical synthesis; transmission electron microscopy;

D O I：

10.1016/j.ssc.2004.05.018

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

We report for the first time direct intercalation of C-60 into graphite. In this new carbon solid, the two dimensional layers of C-60, stacked between every graphite layers (stage 1), showed long range ordering with average separation of 1.27 nm between C-60 layers as evident from transmission electron microscopy. An up-shift of Graphite Raman E-2g2 mode and down-shift of fullerenes Raman A(g2) pentagonal pinch mode was observed due to charge transfer from graphite to C-60. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：153 / 155

页数：3

共 13 条

[1] ELECTRONIC STATES OF KXC60 - INSULATING, METALLIC, AND SUPERCONDUCTING CHARACTER [J].