High performance silicon carbon composite anode materials for lithium ion batteries

被引:61
作者
Luo, Zhaojun [1 ]
Fan, Dongdong [1 ]
Liu, Xianlong [1 ]
Mao, Huanyu [1 ]
Yao, Caifang [1 ]
Deng, Zhongyi [1 ]
机构
[1] Shenzhen BAK Battery Co Ltd, Shenzhen, Peoples R China
关键词
Silicon powder; Silicon carbon composite; Lithium ion battery; Anode material; AMORPHOUS-SILICON;
D O I
10.1016/j.jpowsour.2008.12.068
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Silicon and silicon containing compounds are attractive anode materials for lithium batteries because of their low electrochemical potential vs. lithium and high theoretical capacities. In this work the relationship between the electrochemical performance of silicon powders and their particle sizes was studied. It is found that the material with nano particle sizes gives the best performance. New silicon/carbon composite anode materials were synthesized and their structures and electrochemical performance were investigated. The results of these studies are reported in this paper. Crown Copyright (C) 2008 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:16 / 21
页数:6
相关论文
共 10 条
[1]   In situ XRD and electrochemical study of the reaction of lithium with amorphous silicon [J].
Hatchard, TD ;
Dahn, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (06) :A838-A842
[2]   Synthesis and electrochemical properties of nanocrystalline Li[NixLi(1-2x)/3Mn(2-x)/3]O2 prepared by a simple combustion method [J].
Hong, YS ;
Park, YJ ;
Ryu, KS ;
Chang, SH ;
Kim, MG .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (09) :1424-1429
[3]   Preparation of polypyrrole-coated silicon nanoparticles [J].
La, HS ;
Park, KS ;
Nahm, KS ;
Jeong, KK ;
Lee, YS .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2006, 272 (1-2) :22-26
[4]   Spherical silicon/graphite/carbon composites as anode material for lithium-ion batteries [J].
Lee, Jong-Hyuk ;
Kim, Wan-Jun ;
Kim, Jae-Youn ;
Lim, Sung-Hwan ;
Lee, Sung-Man .
JOURNAL OF POWER SOURCES, 2008, 176 (01) :353-358
[5]   The formation and properties of amorphous silicon as negative electrode reactant in lithium systems [J].
Netz, A ;
Huggins, RA ;
Weppner, W .
JOURNAL OF POWER SOURCES, 2003, 119 :95-100
[6]   Structural changes in silicon anodes during lithium insertion/extraction [J].
Obrovac, MN ;
Christensen, L .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (05) :A93-A96
[7]   Li4Ti5O12 as anode in all-solid-state, plastic, lithium-ion batteries for low-power applications [J].
Prosini, PP ;
Mancini, R ;
Petrucci, L ;
Contini, V ;
Villano, P .
SOLID STATE IONICS, 2001, 144 (1-2) :185-192
[8]   Characterization of LiFePO4 as the cathode material for rechargeable lithium batteries [J].
Takahashi, M ;
Tobishima, S ;
Takei, K ;
Sakurai, Y .
JOURNAL OF POWER SOURCES, 2001, 97-8 :508-511
[9]   Electrochemical behaviors of silicon based anode material [J].
Yoshio, M ;
Tsumura, T ;
Dimov, N .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :10-14
[10]   Electrochemical stability of silicon/carbon composite anode for lithium ion batteries [J].
Zuo, Pengjian ;
Yin, Geping ;
Ma, Yulin .
ELECTROCHIMICA ACTA, 2007, 52 (15) :4878-4883