An investigation into alkenyl-functionalized 1,4,7-triazacyclononanes: Synthesis, metal complexation, and attempted olefin metathesis

被引：11

作者：

Baker, MV ^{[1
]}

Brown, DH ^{[1
]}

Skelton, BW ^{[1
]}

White, AH ^{[1
]}

机构：

[1] Univ Western Australia, Dept Chem, Crawley, WA 6009, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 10期

关键词：

D O I：

10.1071/CH02063

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two triazacyclononanes bearing pendant alkenyl groups [1,4, 7- tri(3-butenyl)-1,4, 7- triazacyclononane and 1, 4,7- tri(2-propenyl)- 1,4,7-triazacyclononane] were synthesized. These triazacyclononanes reacted with nickel salts to form dinuclear complexes [(R(3)TACN)Ni(mu-Cl)(3) Ni(R(3)TACN)](+), various salts of which have been structurally characterized. Attempts to perform intramolecular olefin metathesis reactions on the pendant alkenes in these complexes were unsuccessful.

引用

页码：655 / 660

页数：6

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