Progress and future prospects of high-voltage and high-safety electrolytes in advanced lithium batteries: from liquid to solid electrolytes

被引：377

作者：

Chen, Shimou ^{[1
]}

Wen, Kaihua ^{[1
,2
]}

Fan, Juntian ^{[1
,2
]}

Bando, Yoshio ^{[3
,4
]}

Golberg, Dmitri ^{[3
,5
]}

机构：

[1] Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, CAS Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] NIMS, Int Ctr Mat Nanoarchitecton MANA, Namiki 1-1, Tsukuba, Ibaraki 3050044, Japan

[4] UOW, AIIM, Squires Way, North Wollongong, NSW 2500, Australia

[5] QUT, Sch Phys Chem & Mech Engn, Sci & Engn Fac, 2nd Georgest, Brisbane, Qld 4070, Australia

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2018年 / 6卷 / 25期

基金：

澳大利亚研究理事会; 中国国家自然科学基金;

关键词：

COMPOSITE POLYMER ELECTROLYTES; LI-ION BATTERIES; SULFONE-BASED ELECTROLYTES; CARBONATE-BASED ELECTROLYTES; ATOMIC LAYER DEPOSITION; PROPYLENE CARBONATE; HIGH-PERFORMANCE; ELECTROCHEMICAL PERFORMANCE; TRANSPORT-PROPERTIES; MECHANICAL-PROPERTIES;

D O I：

10.1039/c8ta03358g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

Developing the next-generation high-energy density and safe batteries is of prime importance to meet the emerging demands in electronics, automobile industries and various energy storage systems. High-voltage lithium-ion batteries (LIBs) and solid-state batteries (SSBs) are two main directions attracting increasing interest in recent years, due to their potential applications in the near future. In both kinds of batteries, the electrolytes play a pivotal role but also create several bottleneck problems. In this review, recent progress in designing electrolytes for high-voltage LIBs and SSBs is summarized. First, the solvents, additives, ionic liquids and superconcentrated salts strategies for constructing high-voltage liquid electrolytes are reviewed, and then the applications of inorganic solids, solid polymers, gels and ionic liquids in solid-state electrolytes are presented. Finally, the general design rules of the electrolytes and their current limitations and future prospects are briefly discussed.

引用

页码：11631 / 11663

页数：33

共 308 条

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Ionic Liquid-Organic Carbonate Electrolyte Blends To Stabilize Silicon Electrodes for Extending Lithium Ion Battery Operability to 100 °C [J].