Synthesis of 6-deoxy-homoDMDP and its C(5)-epimer:: absolute stereochemistry of natural products from Hyacinthus orientalis

被引：18

作者：

Behr, JB ^{[1
]}

Guillerm, G ^{[1
]}

机构：

[1] UFR Sci, Lab Chim Bioorgan, UMR 6519, F-51687 Reims 2, France

来源：

TETRAHEDRON-ASYMMETRY | 2002年 / 13卷 / 02期

关键词：

D O I：

10.1016/S0957-4166(02)00081-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A concise enantioselective synthesis of 2,5-imino-2,5,6-trideoxy-D-manno-heptitol (6-deoxy-homoDMDP) and 2,5-imino-2,5,6-trideoxy-L-gulo-heptitol has been achieved. These compounds were used as stereochemical references to establish the absolute configuration of the corresponding naturally occurring stereoisomers, recently isolated from Hyacinthus orientalis. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：111 / 113

页数：3

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