Further developments in metal-catalysed C-C bond cleavage in allylic dimethyl malonate derivatives

被引：28

作者：

Bricout, H ^{[1
]}

Carpentier, JF ^{[1
]}

Mortreux, A ^{[1
]}

机构：

[1] ENSCL, CATALYSE HETEROGENE & HOMOGENE LAB, CNRS, GRP CHIM ORGAN APPL, F-59652 VILLENEUVE DASCQ, FRANCE

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 06期

关键词：

D O I：

10.1016/S0040-4039(96)02510-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The use of a catalytic amount of nickelbis(1,4-bis(diphenylphosphino)butane) in DMF enables the activation of the C-C bond in dimethyl allylmalonate derivatives to proceed under rather smooth reaction conditions, without added nucleophile. Several examples like isomerization of substituted-allyl malonate derivatives, racemization of chiral products, but also a synthetic application as an inverse disproportionation reaction are described. (C) 1997, Elsevier Science Ltd.

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页码：1053 / 1056

页数：4

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