Asymmetric Oxidation of o-Alkylphenols with Chiral 2-(o-Iodoxyphenyl)-oxazolines

被引：123

作者：

Boppisetti, Jagadish K. ^{[1
]}

Birman, Vladimir B. ^{[1
]}

机构：

[1] Washington Univ, Dept Chem, St Louis, MO 63130 USA

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 06期

关键词：

HYPERVALENT IODINE(V) REAGENTS; IODOXYBENZOIC ACID IBX; ORGANIC-SYNTHESIS; PHENOL DEAROMATIZATION; OXIDIZING REAGENTS; CHEMISTRY; ORTHOQUINOLS; DIMERIZATION; ALCOHOLS; BENZENE;

D O I：

10.1021/ol8029092

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new class of chiral iodine(V) derivatives has been prepared. These compounds have been found to transform ortho-alkylphenols into ortho-quinol Diels-Alder dimers with significant levels of asymmetric induction.

引用

页码：1221 / 1223

页数：3

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