Molecular beam studies of gas-liquid interfaces

被引：157

作者：

Nathanson, GM ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

ANNUAL REVIEW OF PHYSICAL CHEMISTRY | 2004年 / 55卷

关键词：

liquid surfaces; gas-surface scattering; hydrogen bonding; proton exchange; molecular energy transfer; heterogeneous atmospheric reactions;

D O I：

10.1146/annurev.physchem.55.091602.094357

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molecular beam scattering experiments provide a way to disentangle the elementary steps involved in energy transfer and chemical reactions between gases and liquids. After surveying the history and recent progress in this field, we review studies of the kinematics of gas-liquid collisions and proton exchange of HCl, DCI, and HBr with supercooled sulfuric acid and liquid glycerol. These experiments help to clarify the role of the surface region in controlling trapping and interfacial- and bulk-phase reactions.

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页码：231 / 255

页数：29

相关论文

共 130 条

[1] Heterogeneous interactions of HBr and HOCl with cold sulfuric acid solutions: Implications for arctic boundary layer bromine chemistry [J].

Abbatt, JPD ;

Nowak, JB .

JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (11) :2131-2137

[2] Impact collision ion scattering spectroscopy (ICISS) and neutral impact collision ion scattering spectroscopy (NICISS) at surfaces of organic liquids [J].

Andersson, G ;

Morgner, H .

SURFACE SCIENCE, 1998, 405 (01) :138-151

[3] Molecular beam studies of HCl interactions with pure and HCl-covered ice surfaces [J].

Andersson, PU ;

Någård, MB ;

Pettersson, JBC .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (07) :1596-1601

[4] Dynamics of argon collisions with water ice:: Molecular beam experiments and molecular dynamics simulations [J].

Andersson, PU ;

Någård, MB ;

Bolton, K ;

Svanberg, M ;

Pettersson, JBC .

JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (12) :2681-2688

[5]

[Anonymous], SURFACE SCI REPT

[6] Sum frequency generation investigation of glycerol/water surfaces [J].

Baldelli, S ;

Schnitzer, C ;

Shultz, MJ ;

Campbell, DJ .

JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (23) :4607-4612

[7] REACTIONS OF CHLORINE WITH LIQUID-METALS .1. INDIUM [J].

BALOOCH, M ;

SIEKHAUS, WJ ;

OLANDER, DR .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (16) :3521-3528

[8]

BALOOCH M, 1986, J PHYS CHEM-US, V90, P1671, DOI 10.1021/j100399a043

[9] Permeation through monolayers [J].

Barnes, GT .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1997, 126 (2-3) :149-158

[10] LASER AND ION-BEAM STUDIES OF LIQUID-SODIUM SURFACE-CHEMISTRY AND NA-2 EVAPORATION [J].

BECKER, CH .

SURFACE SCIENCE, 1985, 149 (01) :67-80

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