Molecular beam studies of gas-liquid interfaces

被引：157

作者：

Nathanson, GM ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

ANNUAL REVIEW OF PHYSICAL CHEMISTRY | 2004年 / 55卷

关键词：

liquid surfaces; gas-surface scattering; hydrogen bonding; proton exchange; molecular energy transfer; heterogeneous atmospheric reactions;

D O I：

10.1146/annurev.physchem.55.091602.094357

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molecular beam scattering experiments provide a way to disentangle the elementary steps involved in energy transfer and chemical reactions between gases and liquids. After surveying the history and recent progress in this field, we review studies of the kinematics of gas-liquid collisions and proton exchange of HCl, DCI, and HBr with supercooled sulfuric acid and liquid glycerol. These experiments help to clarify the role of the surface region in controlling trapping and interfacial- and bulk-phase reactions.

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页码：231 / 255

页数：29

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