Facile one-pot synthesis of brush polymers through tandem catalysis using Grubbs' catalyst for both ring-opening metathesis and atom transfer radical polymerizations

被引：125

作者：

Cheng, Chong

Khoshdel, Ezat

Wooley, Karen L.

机构：

[1] Washington Univ, Ctr Mat Innovat, St Louis, MO 63130 USA

[2] Washington Univ, Dept Chem, St Louis, MO 63130 USA

[3] Unilever, Bebington CH63 3JW, England

来源：

NANO LETTERS | 2006年 / 6卷 / 08期

基金：

美国国家科学基金会;

关键词：

SCANNING FORCE MICROSCOPY; MOLECULAR BRUSHES; VINYL MONOMERS; COPOLYMERS; COMPLEXES; ROMP; MACROMOLECULES; MORPHOLOGY; ASSEMBLIES; REACTIVITY;

D O I：

10.1021/nl0611900

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using Grubbs' catalyst Cl-2(PCy3)(2)Ru=CHPh for tandem catalysis, poly(methyl methacrylate)-based brush polymers were prepared by one-pot sequential ring-opening metathesis polymerization (ROMP) and atom transfer radical polymerization (ATRP) via an inimer having both an alpha-bromoisobutyrate ATRP initiator functionality and an exo-norbornenyl ROMP monomer functionality. The surface morphologies and aggregation behaviors of these nanoscopic single molecules were studied by tapping-mode atomic force microscopy measurements on mica.

引用

收藏

页码：1741 / 1746

页数：6

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