Synthesis of branched poly(methyl methacrylate)s via controlled/living polymerisations exploiting ethylene glycol dimethacrylate as branching agent

被引：162

作者：

Isaure, F

Cormack, PAG

Graham, S

Sherrington, DC

Armes, SP

Bütün, V

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

[2] Univ Sussex, Sch Life Sci, Dept Chem, Brighton BN1 9QJ, E Sussex, England

[3] Osmangazi Univ, Fac Arts & Sci, Dept Chem, TR-26480 Eskisehir, Turkey

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 09期

关键词：

D O I：

10.1039/b401709a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

With appropriate choice of reaction composition and conditions, copolymerisation of methyl methacrylate and ethylene glycol dimethacrylate using Cu-based ATRP or GTP methodologies yields soluble branched polymers in facile one-pot reactions.

引用

页码：1138 / 1139

页数：2

共 19 条

[1] Controlling the degree of branching in vinyl polymerization [J].

Ambade, AV ;

Kumar, A .

PROGRESS IN POLYMER SCIENCE, 2000, 25 (08) :1141-1170

[2] Hyperbranched polymers from divinylbenzene and 1,3-diisopropenylbenzene through anionic self-condensing vinyl polymerization [J].

Baskaran, D .

POLYMER, 2003, 44 (08) :2213-2220

[3] Synthesis and aqueous solution properties of near-monodisperse tertiary amine methacrylate homopolymers and diblock copolymers [J].

Bütün, V ;

Armes, SP ;

Billingham, NC .

POLYMER, 2001, 42 (14) :5993-6008

[4]

CHISHOLM MS, 1999, Patent No. 9946301

[5] Branched methacrylate copolymers from multifunctional monomers: chemical composition and physical architecture distributions [J].

Costello, PA ;

Martin, IK ;

Slark, AT ;

Sherrington, DC ;

Titterton, A .

POLYMER, 2002, 43 (02) :245-254

[6] OXYANIONS CATALYZE GROUP-TRANSFER POLYMERIZATION TO GIVE LIVING POLYMERS [J].

DICKER, IB ;

COHEN, GM ;

FARNHAM, WB ;

HERTLER, WR ;

LAGANIS, ED ;

SOGAH, DY .

MACROMOLECULES, 1990, 23 (18) :4034-4041

[7] Molecular size distribution in three dimensional polymers. III. Tetrafunctional branching units [J].

Flory, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1941, 63 :3096-3100

[8] Molecular size distribution in three dimensional polymers. I. Gelation [J].

Flory, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1941, 63 :3083-3090

[9] Molecular size distribution in three dimensional polymers. II. Trifunctional branching units [J].

Flory, PJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1941, 63 :3091-3096

[10] SELF-CONDENSING VINYL POLYMERIZATION - AN APPROACH TO DENDRITIC MATERIALS [J].

FRECHET, JMJ ;

HENMI, M ;

GITSOV, I ;

AOSHIMA, S ;

LEDUC, MR ;

GRUBBS, RB .

SCIENCE, 1995, 269 (5227) :1080-1083

← 1 2 →