Controlling the degree of branching in vinyl polymerization

被引：60

作者：

Ambade, AV ^{[1
]}

Kumar, A ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

来源：

PROGRESS IN POLYMER SCIENCE | 2000年 / 25卷 / 08期

关键词：

self-condensing vinyl polymerization; atom transfer radical polymerization; hyperbranched polymers; vinyl polymerization; living free radical polymerization;

D O I：

10.1016/S0079-6700(00)00023-X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 [高分子化学与物理]; 080501 [材料物理与化学]; 081704 [应用化学];

摘要：

Branching is an important tool for a synthetic polymer chemist in order to control the macroscopic properties of polymers. In condensation polymers, branching can be controlled by copolymerization of an AB? type monomer with an AB type monomer. However, in Vinyl polymerizations, it was not until very recently that the degree of branching could be controlled. Two different approaches, namely, Self-Condensing Vinyl Polymerization (SCVP) and Atom Transfer Radical Polymerization (ATRP) were developed for controlling the degree of branching in vinyl systems. This review article highlights recent advances in the science and technology in these two industrially very important approaches. A brief summary at the end highlights the advantages and disadvantages of each methodology. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：1141 / 1170

页数：30

共 151 条

[1]

Living radical polymerization of methyl methacrylate with ruthenium complex: Formation of polymers with controlled molecular weights and very narrow distributions [J].

Ando, T ;

Kato, M ;

Kamigaito, M ;

Sawamoto, M .

MACROMOLECULES, 1996, 29 (03) :1070-1072

[2]

Design of initiators for living radical polymerization of methyl methacrylate mediated by ruthenium(II) complex [J].

Ando, T ;

Kamigaito, M ;

Sawamoto, M .

TETRAHEDRON, 1997, 53 (45) :15445-15457

[3]

Iron(II) chloride complex for living radical polymerization of methyl methacrylate [J].

Ando, T ;

Kamigaito, M ;

Sawamoto, M .

MACROMOLECULES, 1997, 30 (16) :4507-4510

[4]

Atom transfer radical polymerization of styrene using a novel octafunctional initiator: Synthesis of well-defined polystyrene stars [J].

Angot, S ;

Murthy, KS ;

Taton, D ;

Gnanou, Y .

MACROMOLECULES, 1998, 31 (21) :7218-7225

[5]

Atom transfer radical copolymerization of styrene and n-butyl acrylate [J].

Arehart, SV ;

Matyjaszewski, K .

MACROMOLECULES, 1999, 32 (07) :2221-2231

[6]

Synthesis of polymer networks by "Living" free radical polymerization and end-linking processes [J].

Asgarzadeh, F ;

Ourdouillie, P ;

Beyou, E ;

Chaumont, P .

MACROMOLECULES, 1999, 32 (21) :6996-7002

[7]

Bednarek M, 1999, MACROMOL RAPID COMM, V20, P59, DOI 10.1002/(SICI)1521-3927(19990201)20:2<59::AID-MARC59>3.0.CO

[8]

2-B

[9]

Atom transfer radical polymerization of 2-hydroxyethyl methacrylate [J].

Beers, KL ;

Boo, S ;

Gaynor, SG ;

Matyjaszewski, K .

MACROMOLECULES, 1999, 32 (18) :5772-5776

[10]

Controlled radical polymerization of styrene in the presence of lithium molybdate(V) complexes and benzylic halides [J].

Brandts, JAM ;

van de Geijn, P ;

van Faassen, EE ;

Boersma, J ;

van Koten, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 584 (02) :246-253

← 1 2 3 4 5 6 7 8 9 10 →