Synthesis of polymer networks by "Living" free radical polymerization and end-linking processes

被引：33

作者：

Asgarzadeh, F ^{[1
]}

Ourdouillie, P ^{[1
]}

Beyou, E ^{[1
]}

Chaumont, P ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, Lab Mat Polymeres & Biomat, UMR Ingn Mat Polymeres 5627, F-69622 Villeurbanne, France

来源：

MACROMOLECULES | 1999年 / 32卷 / 21期

关键词：

D O I：

10.1021/ma990022+

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of polymer networks by controlled free radical polymerization has been investigated in the case of atom transfer radical. polymerization (ATRP). The synthesis of a difunctional initiator, bis(2-bromopropionyloxy) ethane (BBPE) makes possible the preparation of difunctional polymer precursors that can be used to prepare polymer networks by an end-linking process. The gels thus formed have been characterized by the determination of the fraction of polymer precursors unlinked to the crosslinks and by the determination of the swelling equilibrium of the gels in xylene.

引用

页码：6996 / 7002

页数：7

共 34 条

[1] Studies on microgels .3. Synthesis using living free radical polymerization
Abrol, S
Kambouris, PA
Looney, MG
Solomon, DH
[J]. MACROMOLECULAR RAPID COMMUNICATIONS, 1997, 18 (09) : 755 - 760
[2] Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process
Chiefari, J
Chong, YK
Ercole, F
Krstina, J
Jeffery, J
Le, TPT
Mayadunne, RTA
Meijs, GF
Moad, CL
Moad, G
Rizzardo, E
Thang, SH
[J]. MACROMOLECULES, 1998, 31 (16) : 5559 - 5562
[3] A more versatile route to block copolymers and other polymers of complex architecture by living radical polymerization: The RAFT process
Chong, YK
Le, TPT
Moad, G
Rizzardo, E
Thang, SH
[J]. MACROMOLECULES, 1999, 32 (06) : 2071 - 2074
[4] COCA S, 1997, POLYM PREPR AM CHEM, V38, P689
[5] Synthesis of triblock and random copolymers of 4-acetoxystyrene and styrene by living atom transfer radical polymerization
Gao, B
Chen, XY
Ivan, B
Kops, J
Batsberg, W
[J]. POLYMER BULLETIN, 1997, 39 (05) : 559 - 565
[6] Living atom transfer radical polymerization of 4-acetoxystyrene
Gao, B
Chen, XY
Ivan, B
Kops, J
Batsberg, W
[J]. MACROMOLECULAR RAPID COMMUNICATIONS, 1997, 18 (12) : 1095 - 1100
[7] NARROW MOLECULAR-WEIGHT RESINS BY A FREE-RADICAL POLYMERIZATION PROCESS
GEORGES, MK
VEREGIN, RPN
KAZMAIER, PM
HAMER, GK
[J]. MACROMOLECULES, 1993, 26 (11) : 2987 - 2988
[8] Controlled radical polymerization of methacrylic monomers in the presence of a bis(ortho-chelated) arylnickel(II) complex and different activated alkyl halides
Granel, C
Dubois, P
Jerome, R
Teyssie, P
[J]. MACROMOLECULES, 1996, 29 (27) : 8576 - 8582
[9] GRULKE EA, 1989, POLYM HDB, V7, P532
[10] Living diradical polymerization
Hammouch, SO
Catala, JM
[J]. MACROMOLECULAR RAPID COMMUNICATIONS, 1996, 17 (02) : 149 - 154

← 1 2 3 4 →