Zn(II) and Pd(II) complexes of thiosemicarbazone-S-alkyl esters derived from 2/3-formylpyridine

被引:30
作者
Kizilcikli, I [1 ]
Ülküseven, B [1 ]
Dasdemir, Y [1 ]
Akkurt, B [1 ]
机构
[1] Univ Istanbul, Fac Engn, Dept Chem, TR-34850 Istanbul, Turkey
来源
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2004年 / 34卷 / 04期
关键词
polydentate thiosemicarbazones; Zn(H) and Pd(II) complexes;
D O I
10.1081/SIM-120035948
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Representative S-methyl/ethyl-4-H/phenylthiosemicarbazones and their Zn(II) and Pd(II) complexes were synthesized. Characterization of the 1:1 complexes, [Zn(L)Cl-2], [Pd(L)Cl-2], and [Pd(L)Cl]Cl, was accomplished by means of elemental analyses, IR and H-1 NMR spectra. The multidentate S-alkyl thiosemicarbazones coordinate as mono-, bi-, or tridentate ligands depending on the types of the alkyl moiety and metal ion.
引用
收藏
页码:653 / 665
页数:13
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