Sesqui- and diterpenes from the liverwort Gackstroemia decipiens

被引:13
作者
Geis, W [1 ]
Becker, H [1 ]
机构
[1] Univ Saarland, FR 123, D-66041 Saarbrucken, Germany
关键词
Gackstroemia decipiens; Lepidolaenaceae; hepaticae; liverwort rosane; nardosinane farnesane;
D O I
10.1016/S0031-9422(99)00500-2
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Six rosanes, 5 beta,11 beta-dihydroxy-ros-15-ene, 5 beta, 12 beta-dihydroxy-ros-15-ene, 11 beta-hydroxy-7-oxo-rosa-5,15-diene, 1 alpha,5 beta,11 beta-trihydroxy-7-oxo-ros-15-ene, 5 beta,20-epoxy-20-hydroxy-ros-15-ene and 5 beta,20-epoxy-20-methoxy-ros-15-ene along with the enantiomer of the already reported 11 beta-hydroxy-rosa-5,15-diene and the known 5 beta-hydroxy-ros-15-ene have been isolated from the liverwort Gackstroemia decipiens. Furthermore, the sesquiterpenes 3-acetoxy-7,11-dihydroxy-farnesa-1,5,9-triene and 1 beta,10 beta-epoxy-nardosin-7,11-diene were identified. Their structures were elucidated by NMR spectroscopy. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:247 / 252
页数:6
相关论文
共 11 条
[1]  
ADAM KP, 1994, PHYTOCHEMISTRY, V35, P139, DOI 10.1016/S0031-9422(00)90522-3
[2]  
Asakawa Y., 1995, Progress in the Chemistry of Organic Natural Products, V65, P1, DOI 10.1007/978-3-7091-6896-7_1
[3]  
Asakawa Y., 1984, STUDIES CRYPTOGAM SO, P109
[4]  
BOHLMANN F, 1984, LIEBIGS ANN CHEM, P162
[5]   Pinguisane sesquiterpenes from the liverwort Porella navicularis [J].
Bungert, M ;
Gabler, J ;
Adam, KP ;
Zapp, J ;
Becker, H .
PHYTOCHEMISTRY, 1998, 49 (04) :1079-1083
[6]  
CONN PM, 1992, NEUROPROTOCOLS, V1, P1
[7]   MOSS CHEMISTRY AND BIOLOGY RESEARCH GROUP .64. BISBIBENZYLIS AND LIGNANS FROM PELLIA-EPIPHYLLA [J].
CULLMANN, F ;
ADAM, KP ;
BECKER, H .
PHYTOCHEMISTRY, 1993, 34 (03) :831-834
[8]  
GARCIAARENAL M, 1981, AL-QANTARA, V2, P167
[9]   cis-Clerodandes from axenic cultures of the liverwort Scapania nemorea [J].
Geis, W ;
Buschauer, B ;
Becker, H .
PHYTOCHEMISTRY, 1999, 51 (05) :643-649
[10]  
GEIS W, 1999, UNPUB GACKSTROEMIA