Gaussian density fluctuations, mode coupling theory and all that

被引:22
作者
Szamel, G [1 ]
机构
[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
来源
EUROPHYSICS LETTERS | 2004年 / 65卷 / 04期
基金
美国国家科学基金会;
关键词
D O I
10.1209/epl/i2003-10115-2
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We consider a toy model for glassy dynamics of colloidal suspensions: a gle Brownian particle diffusing among immobile obstacles. If Gaussian factorization of static density fluctuations is assumed, this model can be solved without factorization approximation for any dynamic correlation function. The solution differs from that obtained from the ideal mode coupling theory (MCT). The latter is equivalent to including only some positive-definite terms in an expression for the memory function. An approximate re-summation of the complete expression suggests that, under the assumption of Gaussian factorization of static fluctuation mobile particle's motion is always diffusive. In contrast, MCT predicts that the mobile particle becomes localized at a high enough obstacle density. We discuss the implications of these results for models for glassy dynamics.
引用
收藏
页码:498 / 504
页数:7
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