Convenient preparation of mononuclear and dinuclear ruthenium hydride complexes for catalytic application

被引：45

作者：

Busch, S ^{[1
]}

Leitner, W ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 22期

关键词：

D O I：

10.1039/a906580f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mixture of commercially available [Ru(cod)(eta(3)-C4H7)(2)] and PCy3 reacts with H-2 to give [RuH2(H-2)(2)(PCy3)(2)] in high yields, whereas [Ru{Cy2P(CH2)(3)PCy2}(eta(3)-C4H7)(2)] leads to [{Cy2P(CH2)(3)PCy2}RuH(mu-H)(3)Ru(H-2){Cy2P(CH2)(3)PCy2}] under identical conditions; this new synthetic procedure provides convenient access to this type of ruthenium hydrides for investigation of their potential in catalytic reactions like the Murai-reaction.

引用

页码：2305 / 2306

页数：2

共 14 条

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