Reaction between ruthenium(0) complexes and dihalo compounds. A new method for the synthesis of ruthenium olefin metathesis catalysts

被引:136
作者
Belderrain, TR [1 ]
Grubbs, RH [1 ]
机构
[1] CALTECH,ARNOLD & MABEL BECKMAN LABS CHEM SYNTHESIS,DIV CHEM & CHEM ENGN,PASADENA,CA 91125
关键词
D O I
10.1021/om970514f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis of ruthenium carbenes by the reaction of a Ru(0) compound or Ru(0) precursors with dihalo compounds is reported. A new procedure for the preparation of [Ru(H)(2)(H-2)(2)(PCy3)(2)] and the use of this complex as a starting material for the synthesis of ruthenium carbenes are presented.
引用
收藏
页码:4001 / 4003
页数:3
相关论文
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